SHERWIN WILLIAMS CO -- B31W207, PROMAR 200 HIGHLIGHTS INTERIOR (SUPDAT) -- 8010-00N075757
===================== Product Identification ===================== Product ID:B31W207, PROMAR 200 HIGHLIGHTS INTERIOR (SUPDAT) MSDS Date:08/20/1996 FSC:8010 NIIN:00N075757 === Responsible Party === Company Name:SHERWIN WILLIAMS CO Address:101 PROSPECT AVE N W City:CLEVELAND State:OH ZIP:44115 Country:US Info Phone Num:216-566-2902 Emergency Phone Num:216-566-2917 CAGE:54626 === Contractor Identification === Company Name:SHERWIN WILLIAMS COMPANY Address:101 PROSPECT AVE NW City:CLEVELAND State:OH ZIP:44115 Country:US Phone:216-566-2902 CAGE:54626 Company Name:SHERWIN-WILLIAMS CO THE Address:101 PROSPECT AVE NW Box:City:CLEVELAND State:OH ZIP:44115-1042 Country:US Phone:800-251-2486/216-566-2242 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL, 2-(2-BUTOXYETHOXY)-; (2-(2-BUTOXYETHOXY)-ETHANOL) CAS:112-34-5 RTECS #:KJ9100000 Fraction by Wt: 2% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ETHYLENE GLYCOL (SARA 313) (CERCLA). VP:0.12 CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: 3% OSHA PEL:C 50 PPM (MFR) ACGIH TLV:C 50 PPM, VAPOR EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE; (CRISTOBALITE) CAS:14464-46-1 RTECS #:VV7325000 Fraction by Wt: 0.1% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.05 MG/M3 RDUST Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 27% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:SUPDAT:URINARY SYSTEMS. RATS EXPOSED TO TITANIUM DIOXIDE DUST @ 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:EXPOSURE LEVELS ARE NOT ATTAINABLE IN THE WORKPLACE. RTECS #:9999999ZZ Ingred Name:OTHER PREC:SANDING/ABRADING OF DRIED FILM. IF NO SPECIFIC DUSTS ARE LISTED IN INGRED SECTION, THE APPLIC LIMS (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:FOR NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 (TOTAL DUST), 3 MG/M3 (RESPIRABLE FRACTION), OSHA PEL 15 MG/M3 (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:(TOTAL DUST), 5 MG/M3 (RESPIRABLE FRACTION). RTECS #:9999999ZZ Ingred Name:RESP PROT:APPRVD BY NIOSH FOR DUST WHICH MAY BE GENERATED FROM THIS PROD, UNDERLYING PAINT, OR THE ABRASIVE. RTECS #:9999999ZZ Ingred Name:VENT:LIMITS. REFER TO OSHA STANDARDS 1910.94, 1910.107, 1910.108. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:IRRITATION OF EYES, SKIN & UPPER RESP SYS. IN CONFINED AREA VAPORS IN HIGH CONC MAY CAUSE HEADACHE, NAUSEA/DIZZINESS. SIGNS & SYMPS OF OVEREXP:REDNESS & ITCHING OR BURNING SENSATION MAY INDICATE EYE/EXCESS SKIN EXPOSURE. CHRONIC:LONGTERM EXPOSURE TO HIGH LEVELS OF SILICA DUST, WHICH CAN OCCUR (EFTS OF OVEREXP) Explanation of Carcinogenicity:SILICA, CRYSTALLINE-CRISTOBALITE:IARC MONOGRAPHS, SUPP, VOL 7, PG 341, 1987:GROUP 2A. NTP 7TH ANNUAL RPT ON (SUPDAT) Effects of Overexposure:HLTH HAZ:ONLY WHEN SANDING/ABRADING DRY FILM, MAY CAUSE LUNG DMG (SILICOSIS) & POSSIBLY CANCER. ETHYLENE GLYCOL IS CONSIDERED AN ANIMAL TERATOGEN. IT HAS BEEN SHOWN TO CAUSE BIRTH DEFECTS IN RATS & MI CE @ HIGH DOSES WHEN GIVEN IN DRINKING WATER/BY GAVAGE. THERE IS NO EVID TO INDICATE IT CAUSES BIRTH DEFECTS (SUPDAT) Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE CONTAMD CLTHG & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LG AMTS OF WATER FOR @ L ST 15 MINS. GET MEDICAL ATTENTION. INGEST:GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZ ARE PREF. WATER MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT) Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNR CLSD WHEN NOT IN USE. TRANSFER ONLY TO APPRVD CNTNRS W/COMPLETE & APPROP LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. Other Precautions:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID CONT W/SKIN & EYES. THIS COATING MAY CONTAIN MATLS CLASSIFIED AS NUISANCE PARTICULATES (LISTED "AS DUST" IN INGRED SECTION) WHICH MAY BE PRESE NT @ HAZ LEVELS ONLY DURING (ING 8) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR PROPERLY FITTED ORG VAP/PARTICULATE RESP APPRVD BY NIOSH FOR PROT AGAINST MATLS IN INGRED SECTION. WHEN SANDING/ABRADING DRIED FI LM, WEAR A DUST/MIST RESP (ING 11) Ventilation:LOC EXHAUST PREF. GEN EXHAUST ACCEPTABLE IF EXPOS TO MATLS IN INGRED SECTION IS MAINTAINED BELOW APPLIC EXPOS (ING 12) Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health MFR TRADE NAME/PART NO:LATEX SEMI-GLOSS PAINT LUMINOUS WHITE. FIRE FIGHT PROC:PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. EXPLAN OF CARCIN:CARCINS, 1994:ANTIC TO BE CARCIN . EFTS OF OVEREXP:IN HUMANS. PRLNGD OVEREXP TO SOLV INGREDS IN SECTION II MAY CAUSE ADVERSE EFTS TO LIVER & (ING 6) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:1.31 VOC Pounds/Gallon:141 pH:9.5 VOC Grams/Liter:1.18 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:59 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THIS PROD IS NOT HAZ AS DEFINED UNDER RCRA 40 CFR 261. INCIN IN APPRVD FACILITY. DO NOT INCIN CLOSED CONTAINER. DISPOSE OF I/A/W FEDERAL, STATE, AND LOCAL REGULATIONS REGUARDING POLLUTION. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.