AIR PRODUCTS AND CHEMICALS INC. -- HELIUM -- 6830-00-782-2656
===================== Product Identification ===================== Product ID:HELIUM MSDS Date:03/01/1994 FSC:6830 NIIN:00-782-2656 === Responsible Party === Company Name:AIR PRODUCTS AND CHEMICALS INC. Address:7201 HAMILTON BLVD City:ALLENTOWN State:PA ZIP:18195-1501 Country:US Info Phone Num:215-481-4911 Emergency Phone Num:800-523-9374 CAGE:00742 === Contractor Identification === Company Name:AIR PRODUCTS AND CHEMICALS INC Address:7201 HAMILTON BLVD Box:City:ALLENTOWN State:PA ZIP:18195-1501 Country:US Phone:800-345-3148/ 800-752-1597 CAGE:00742 Company Name:AIR PRODUCTS AND CHEMICALS INC Address:2900 52ND AVE Box:City:HYATTSVILLE State:MD ZIP:20781-1103 Country:US Phone:610-481-6333 CAGE:56028 Company Name:SPECIALTY GAS TECHNOLOGY Address:10207-D CHAPEL HILL RD Box:City:MORRISVILLE Phone:800-876-9581 CAGE:0Y5M5 ============= Composition/Information on Ingredients ============= Ingred Name:HELIUM CAS:7440-59-7 RTECS #:MH6520000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:HELIUM IS A SIMPLE ASPHYXIANT. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:HELIUM IS NON-TOXIC, ODORLESS, COLORLESS, NON-FLAMMABLE GAS STORED IN CYLINDERS AT HIGH PRESSURE. IT CAN CAUSE RAPID SUFFOCATION WHEN CONCENTRATIONS ARE SUFFICIENT TO REDUCT OXYGEN LEVELS TO BELOW 19. 5%. IT IT LIGHTER THAN AIR & MAY COLLECT IN HIGH POINTS OR ALONG CIELINGS. SCBA MAY BE REQUIRED BY RESCUE WORKERS. Explanation of Carcinogenicity:HELIUM IN NOT LISTED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY NTP, IARC OR OSHA SUBPART Z. Effects of Overexposure:EYE:NO ADVERSE EFFECT. SKIN:NO ADVERSE EFFECT. INHALATION:NON-TOXIC. MAY CAUSE SUFFOCATION. MAY CAUSE DIZZINESS, NAUSEA, VOMITING, EXCESSIVE SALVATION, DIMINISHED MENTAL ALERTNESS, LOSS OF CONSCIOUSNE SS, DEATH. Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:EYE/SKIN CONTACT:NOT APPLICABLE. INHALATION"PERSONS SUFFERING FROM LACK OF OXYGEN SHOULD BE MOVED TO FRESH AIR. AID OR RESTORE BREATHING AS NEEDED. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Autoignition Temp:Autoignition Temp Text:NONE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:HELIUM IS NON-FLAMMABLE & DOES NOT SUPPORT COMBUSTION. USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:HELIUM IS A SIMPLE ASPHYXIANT. IF POSSIBLE REMOVE HELIUM CYLINDERS FROM FIRE AREA OR COOL W/WATER. SELF-CONTAINED BREATHING APPARATUSMAY BE REQUIRED FOR RESCUE. Unusual Fire/Explosion Hazard:CYLINDER MAY VENT RAPIDLY OR RUPTURE VIOLENTLY. MOST CYLINDERS ARE DESIGNED TO VENT AT ELEVATED TEMPERATURES. CYLINDER MAY RUPTURE IF RELIEF VALVE FAILS. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL PERSONNEL. INCREASE VENTILATION & MONITOR OXYGEN LEVEL. USE SELF-CONTAINED BREATHING APPARATUS. IF LEAK IS FROM CONTAINER OR ITS VALVE, CALL AIR PRODUCTS' EMERGENCY TELEPHONE NUMBER. IF L EAK IS IN USER'S SYSTEM, CLOSE CYLINDER& VENT. Neutralizing Agent:MFR GAVE NO INFORMATION OF MSDS. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE CYLINDERS UPRIGHT IN A WELL VENTILATED, SECURE AREA PROTECTED FROM WEATHER. KEEP TEMPERATURE <125F. AVOID AREAS CORROSIVE TO CYLINDER. Other Precautions:KEEP VALVE PROTECTION CAPS & OUTLET SEALS IN PLACE. SEGREGATE EMPTY & FULL CYLINDERS. AVOID EXCESSIVE INVENTORY AND/OR STORAGE TIME. KEEP GOOD INVENTORY RECORDS. ALWAYS STORE & HANDLE CYLINDERS PER CG A PAMPHLET P-1 & I/A/W LOCAL REGULATIONS ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED. EMERGENCY:USE SELF-CONTAINED BREATHING APPARATUS OR AIR LINE RESPIRATOR WHERE OXYGEN LEVEL IS BELOW 19.5%. AIR PURIFYING RESPIRATORS DO NOT PROVIDE PROTECTION. Ventilation:USE MECHANICAL (GENERAL) VENTILATION & LOCAL EXHAUST TO PREVENT ACCUMULATIONS WHICH REDUCE THE OXYGEN LEVEL BELOW 19.5%. Protective Gloves:MFR GAVE NO INFORMATION OF MSDS. Eye Protection:MFR GAVE NO INFORMATION OF MSDS. Other Protective Equipment:SAFTEY SHOES WHEN HANDLING CYLINDERS. Work Hygienic Practices:DO NOT DRAG OR ROLL CYLINDERS. USE CYLINDER TRUCK TO MOVE CYLINDERS. DO NOT LIFT CYLINDER BY CAP. DO NOT HEAT CYLINDERS. Supplemental Safety and Health USE A CHECK VALVE TO PREVENT REVERSE FLOW. USE A PRESSURE REDUCING VALVE. DO NOT INSERT TOOLS INTO CAP OPENINGS, USE A STRAP WRENCH TO REMOVE OVERTIGHT OR RUSTED CAPS. DO NOT REFILL CYLINDER W/O OWNER 'S WRITTEN CONSENT. SHIPPING SUCH A CYLINDER IS VIOLATION OF DOT REGS. ================== Physical/Chemical Properties ================== HCC:G3 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:-452F,-269C Vapor Density:0.138 Solubility in Water:0.0094% Appearance and Odor:COLORLESS, ODORLESS GAS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:RETURN CONTAINER & UNUSED PRODUCT TO SUPPLIER. DO NOT ATTEMPT TO DISPOSE OF RESIDUAL OR UNUSED QUANTITIES. FOR EMERGENCY DISPOSAL, SECURE THE CYLINDER & SLOWLY DISCHARGE GAS TO ATMOSPHERE IN A WELL VE NTILATED AREA OR OUTDOORS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.