PHILLIPS PETROLEUM CO -- GASOLINE (ALL GRADES) PREMIUM UNLEADED, 130 -- 9140-00N040059
===================== Product Identification ===================== Product ID:GASOLINE (ALL GRADES) PREMIUM UNLEADED, 130 MSDS Date:03/31/1990 FSC:9140 NIIN:00N040059 === Responsible Party === Company Name:PHILLIPS PETROLEUM CO Address:12 D2 PHILLIPS BLDG City:BARTLESVILLE State:OK ZIP:74004 Country:US Info Phone Num:918-661-8327; 918-661-5952 Emergency Phone Num:918-661-3865; 918-661-8118 CAGE:46916 === Contractor Identification === Company Name:PHILLIPS PETROLEUM CO Address:613 ADAMS Box:City:BARTLESVILLE State:OK ZIP:74004 Country:US Phone:800-234-6603 CAGE:46935 Company Name:PHILLIPS PETROLEUM COMPANY CAGE:46916 ============= Composition/Information on Ingredients ============= Ingred Name:ING 12:BENZENE HAS PRDCD FETAL DEATH IN LAB ANIMALS & CAUSED CHROMOSOME CHANGES IN HUMANS & MUTATION CHANGES IN (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:CELLS OF OTHER ORGANISMS. HLTH EFTS ATTRIBUTABLE TO BENZENE ARE NOT KNOWN TO OCCUR IN HUMANS EXPOSED TO (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:GAS.NOTE:TOLUENE(108-88-3)& LEAD CMPD IS ON NAVY LIST OF OCCUP CHEM REPRO HAZS. CONSULT WITH APPROP HLTH(ING 1) RTECS #:9999999ZZ Ingred Name:ING 15:PROFS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS RECS . RTECS #:9999999ZZ Ingred Name:SPILL PROC:TRANSFER TO DISPOSAL DRUMS USING NON-SPARKING EQUIPMENT. RTECS #:9999999ZZ Ingred Name:OTHER PREC:CONTAM EQUIP: CONT IMMED SUPERVISOR FOR SPECIFIC INSTRUCTIONS BEFORE WORK IS INITIATED. WEAR PROT (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:EQUIP &/OR GARMENTS DESCRIBED IN PERSONAL PROT INFO IF EXPOS CNDTNS WARRANT. NOTE: PERSONAL PROT INFO IS (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19:BASED UPON GEN INFO AS TO NORMAL USES & CNDTNS. WHERE SPECIAL/UNUSUAL USES/CNDTNS EXIST, IT IS SUGGESTED (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20:THAT EXPERT ASSISTANCE OF INDUS HYGIENIST/OTHER QUALIFIED PROF BE SOUGHT. RTECS #:9999999ZZ Ingred Name:GASOLINE (INCLUDING INGREDIENTS 2 - 9) CAS:8006-61-9 RTECS #:LX3300000 Fraction by Wt: 100% OSHA PEL:300 PPM;500 PPM STEL ACGIH TLV:300 PPM;500 PPM STEL Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: <5% OSHA PEL:1 PPM;5 PPM STEL ACGIH TLV:10 PPM EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: <10% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZENE, ETHYL-; (ETHYL BENZENE) (SARA III) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: <2% OSHA PEL:100 PPM;125 PPM STEL ACGIH TLV:100 PPM;125 PPM STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:P-XYLENE (SARA III) CAS:106-42-3 RTECS #:ZE2625000 Fraction by Wt: <3% OSHA PEL:100 PPM;150 PPM STEL ACGIH TLV:100 PPM;150 PPM STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:M-XYLENE (SARA III) CAS:108-38-3 RTECS #:ZE2275000 Fraction by Wt: <6% OSHA PEL:100 PPM;150 PPM STEL ACGIH TLV:100 PPM;150 PPM STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:O-XYLENE (SARA III) CAS:95-47-6 RTECS #:ZE2450000 Fraction by Wt: <3% OSHA PEL:100 PPM;150 PPM STEL ACGIH TLV:100 PPM;150 PPM STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHER, TERT-BUTYL METHYL; (METHYL TERT-BUTYL ETHER) (SARA III) CAS:1634-04-4 RTECS #:KN5250000 Fraction by Wt: <15% EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:BENZENE, 1,2,4-TRIMETHYL-; (1,2,4-TRIMETHYLBENZENE) (SARA III) CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: <3% OSHA PEL:25 PPM ACGIH TLV:25 PPM Ingred Name:PLUMBANE, TETRAETHYL; (TETRAETHYL LEAD) (SARA III) CAS:78-00-2 RTECS #:TP4550000 Fraction by Wt: <0.25% OSHA PEL:0.075 MG/M3, S ACGIH TLV:0.1 MG/M3, S EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:EFTS OF OVEREXP:NERVES, KIDNEYS & REPRO SYS. BENZENE MAY PRDCE BLOOD CHANGES WHICH INCL REDUCED PLATELETS, (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:REDUCED RED BLOOD CELLS, REDUCED WHITE BLOOD CELLS, APLASTIC ANEMIA & ACUTE NONLYMPHOCYTIC LEUKEMIA. (ING 13) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE:EYE/SKIN:MAY CAUSE SLIGHT IRRIT. INHAL:MAY CAUSE HDCH, NAUS, WEAK, SEDATION & UNCON. INGEST:MAY CAUSE IRRIT TO INTESTINES. MAY BE ASPIR INTO LUNGS IF SWALLOWED, WHICH MAY RSLT IN PULM EDEMA & CH EM PNEUM. CHRONIC:UNLEADED GAS HAS PRDCD CANCER IN LAB ANIMALS. NO COMPARABLE HLTH HAZ FOR CANCER IS (EFTS OF OVEREXP) Explanation of Carcinogenicity:BENZENE:KNOWN CARCIN(NTP)5'TH ANN RPT ON CARCIN:GRP 1(IARC)MONO.VOL SUP 7,P.120,'87;OSHA REGULTD CARCIN,2ACFR,1910.1028. Effects of Overexposure:HLTH HAZ:KNOWN TO OCCUR IN HUMANS. UNLEADED GAS HAS PRDCD KIDNEY DMG IN MALE RATS ONLY. NO COMPARABLE HLTH HAZ FOR KIDNEY DISEASE IS KNOWN TO OCCUR IN HUMANS. GAS CNTNG LEAD ANTI-KNOCK CMPDS SHLD BE H NDLD IN SUCH A WAY TO MIN CONT W/BODY. LEAD CAN ACCUM IN BODY W/OVEREXP & CAUSE ILLNESS DUE TO EFTS ON BLOOD, (ING 11) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/RUNNING WATER FOR AT LST 15 MINS. IF IRRIT DEVELOPS, SEEK MED ATTN. SKIN:WASH W/SOAP & WATER. IF IRRIT DEVELOPS, SEEK MED ATTN. INHAL:REMOVE FROM EXPOS. IF BRTHG CEASES, ADMIN ARTF RESP FO LLOWED BY OXYGEN. SEEK MED ATTN. INGEST:DO NOT INDUCE VOMIT. SEEK IMMED MED ASSISTANCE. NOTE TO MD:GASTRIC LAVAGE USING CUFFED ENDOTRACHEAL TUBE MAY BE PERFORMED AT YOUR DISCRETION. ===================== Fire Fighting Measures ===================== Flash Point:<-35F,<-37C Lower Limits:1.5% Upper Limits:7.6% Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE (CO*2). Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . EVACUATE AREA OF ALL UNNEC PERS. SHUT OFF SOURCE, IF POSS. WATER FOG/SPRAY MAY BE USED TO COOL (SUPDAT) Unusual Fire/Explosion Hazard:CARBON OXIDES & VARIOUS HYDROCARBONS FORMED WHEN BURNED. GASOLINES CNTNG TETRAETHYL LEAD WILL FORM LEAD FUMES WHEN BURNING. HIGHLY FLAMM VAPS WHICH ARE (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA OF ALL UNNEC PERS. WEAR PROT EQUIP &/OR GARMENTS DESCRIBED IN PERSONAL PROT INFO IF EXPOS CNDTNS WARRANT. SHUT OFF SOURCE, IF POSS & CONTAIN SPILL. PROT FROM IGNIT. KEEP OUT OF WATER SOU RCES & SEWERS. ABSORB IN DRY, INERT MATL. (ING 17) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:AVOID CONT W/EYES, SKIN/CLTHG. AVOID BRTHG VAPS. WEAR PROT EQUIP &/OR GARMENTS DESCRIBED IN PERSONAL PROT INFO IF EXPOS CNDTNS WARRANT. Other Precautions:DO NOT SIPHON BY MOUTH. STORE IN COOL, WELL-VENTED AREA AWAY FROM IGNIT SOURCES. PROVIDE MEANS OF CONTROLLING LEAKS & SPILLS. BOND & GROUND DURING LIQ TRANSFER. KEEP CNTNRS CLSD. PROT CNTNRS FROM PHYS ICAL DMG. PROT REQD FOR WORK ON (ING 18) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR CONCENTRATIONS EXCEEDING RECOMMENDED EXPOSURE LEVEL, USE NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR. WHEN ENTRY INTO/EXIT FROM CONCENTRATIONS OF UNKNOWN EXPOSURE, USE NIOSH/MSHA APPROVED SCBA. Ventilation:USE ADEQUATE VENTILATION TO CONTROL EXPOSURE BELOW RECOMMENDED LEVELS. Protective Gloves:VITON, NITRILE/POLYVINYL ALCHOHOL (PVA). Eye Protection:CHEMICAL WORKERS GOGGLES . Other Protective Equipment:FULL BODY LONG-SLEEVED GARMENTS. Work Hygienic Practices:WASH THORO AFTER HANDLING. IMMED REMOVE ANY CONTAM CLOTHING. LAUNDER CONTAM CLOTHING BEFORE REUSE. Supplemental Safety and Health VP:350-800 @ 20C. FL PT METH:ESTIMATED. FIRE FIGHT PROC:EXPOSED CNTNRS & EQUIP. DO NOT SPRAY WATER DIRECTLY ON FIRE - PROD WILL FLOAT & COULD BE REIGNITED ON SURF OF WATER. EXPLO HAZ:HVR/AIR MAY ACCUM IN LOW AREAS &/OR SPREAD ALONG GROUND AWAY FROM HNDLG SITE. FLASHBACK ALONG VAP TRAIL MAY OCCUR. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>80F,>27C Vapor Pres:SUPP DATA Vapor Density:3-4 Spec Gravity:0.8 (H*2O=1) Evaporation Rate & Reference:>1 (BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:RED-ORANGE LIQUID; PUNGENT ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXYGEN & STRONG OXIDIZING AGENTS. Hazardous Decomposition Products:CARBON OXIDES, LEAD FUMES (FOR GRADES CNTNG TETRAETHYL LEAD) & VARIOUS HYDROCARBONS WHEN BURNED. ==================== Disposal Considerations ==================== Waste Disposal Methods:INSURE CONFORMITY W/ALL APPLIC FED, STATE & LOCAL DISP REGS. INCIN/OTHERWISE MANAGE IN RCRA PERMITTED WASTE MANAGEMENT FACILITY. RCRA CLASS - UNADULTERATED PROD AS WASTE:D001, FOR ALL GASOLINES; D008, FOR GAS CNTNG TETRAETHYL LEAD. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.