FOX VALLEY SYSTEMS INC -- SUPER SUPREME TRAFFIC PAINT YELLOW, STYW2D -- -
===================== Product Identification ===================== Product ID:SUPER SUPREME TRAFFIC PAINT YELLOW, STYW2D MSDS Date:01/01/1998 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:FOX VALLEY SYSTEMS INC Address:640 INDUSTRIAL DR City:CARY State:IL ZIP:60013 Country:US Info Phone Num:847-639-5744 Emergency Phone Num:847-639-5744 Resp. Party Other MSDS Num.:95MSDS1 CAGE:1BF99 === Contractor Identification === Company Name:FOX VALLEY SYSTEMS INC Address:640 INDUSTRIAL DR Box:City:CARY State:IL ZIP:60013 Country:US Phone:847-639-5744 CAGE:1BF99 ============= Composition/Information on Ingredients ============= Ingred Name:2-BUTOXYETHANOL CAS:111-76-2 RTECS #:KJ8575000 Minumum % Wt:1. Maxumum % Wt:5. OSHA PEL:240 MG/M3;50 PPM ACGIH TLV:121 MG/M3;25 PPM Ingred Name:BUTANE CAS:106-97-8 RTECS #:EJ4200000 Minumum % Wt:1. Maxumum % Wt:5. ACGIH TLV:1900 MG/M3;800 PPM Ingred Name:ISOBUTANE CAS:75-28-5 RTECS #:TI4300000 Minumum % Wt:10. Maxumum % Wt:20. Ingred Name:BENZIN; (PETROLEUM NAPHTHA) CAS:8030-30-6 RTECS #:DE3030000 Minumum % Wt:1. Maxumum % Wt:5. OSHA PEL:400 MG/M3;100 PPM ACGIH TLV:1590 MG/M3;400 PPM Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Minumum % Wt:5. Maxumum % Wt:15. OSHA PEL:1800 MG/M3;1000 PPM Ingred Name:TOLUENE CAS:108-88-3 RTECS #:XS5250000 Minumum % Wt:10. Maxumum % Wt:20. OSHA PEL:see Table Z-2 ACGIH TLV:188 MG/M3;50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:LIGHT ALIPHATIC SOLVENT NAPHTHA (PETROLEUM); (VM & P NAPHTHA) CAS:64742-89-8 Minumum % Wt:5. Maxumum % Wt:15. Ingred Name:XYLENE CAS:1330-20-7 RTECS #:ZE2100000 Minumum % Wt:3. Maxumum % Wt:10. ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:651 MG/M3;150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYLBENZENE CAS:100-41-4 RTECS #:DA0700000 Minumum % Wt:1. Maxumum % Wt:2. OSHA PEL:435 MG/M3;100 PPM ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:543 MG/M3;125 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ANTIMONY(3+) OXIDE CAS:1309-64-4 RTECS #:CC5650000 = Wt:1.25 OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:C.I. PIGMENT YELLOW 34; (LEAD SULFOCHROMATE) (0.05 MG/M3 AS PB AND 0.1 MG/M3 AS CRO*3) CAS:1344-37-2 RTECS #:GE4599900 Minumum % Wt:17. Maxumum % Wt:20. Ingred Name:MOLYBDATE ORANGE; (LEAD MOLYBDATE CHROMATE SULFATE) (0.05 MG/M3 AS PB AND 0.1 MG/M3 AS CR) CAS:12656-85-8 RTECS #:QA4660000 < Wt:.5 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:PRODUCT CONTAINS LEAD CHROMATES. DRIED FILM OF THIS PAINT MAY BE HARMFUL/FATAL IF EATEN/CHEWED. CONTACT W/BROKEN SKIN/ INHALATION OF SPRAY MIST/SANDING DUST MAY CAUSE SEVERE BODILY HARM. USE W/ADEQUAT E VENTILATION. LEAD CHROMATE IS A SUSPECT CANCER HAZARD. RISK OF CANCER DEPENDS ON DURATION & LEVEL OF EXPOSURE. PROLONGED/REPEATED INHALATION & INGESTION. SUCH AS FROM POOR HYGIENE. HOUSEKEEPING/HAND LING PRACTICES. CAN RESULT IN LEAD POISONING. EFECTS OF OVEREXPOSURE: EYES: MAY CAUSE IRRITATION, REDNESS, TEARING, BLURRED VISION & CONJUNCTIVITIS. SKIN: PROLONGED/REPEATED CONTACT MAY CAUSE MODERATE IRRITATION. (EFTS OF OVEREXP) Explanation of Carcinogenicity:ANTIMONY OXIDE: IARC MONOGRAPHS; VOL. 47, PG 291: 1989: GROUP 2B. MOLYBDATE ORANGE: IARC MONOGRAPHS, VOL. 49, PG. 49: 1990: GROUP 1. LEAD CHROMATE (IN PIGMENTS): IARC GROUP 1, SUP 7, P 165, 1987; K NOWN CARCINOGEN, NTP 8TH ANNUAL REPORT, 1998. Effects of Overexposure:HLTH HAZ: DEFAT DERM & ABSORPTION THRU SKIN IN TOX AMTS. INHAL: EXCESSIVE INHAL OF VAPS MAY CAUSE HDCH, NAUSEA, DROW, IRRIT OF MUC MEMB OF NOSE & THROAT. RESP IRRIT & ALSO ALLERGIC REACTION. INGEST: M AY CAUSE NAUSEA. ANIMAL STUDIES CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE AFFECTS ON CNS, HEMATOPIETIC TISSUES, BLOOD, KIDNEYS & LIVER, ASSOCIATED W/ADMINISTRATION OF ETHYLENE GLYCOL MONOBUTYL ETHER ( EGBE). (EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO. 90-118) . TOLUENE & LEAD APPEAR ON NAVY OCCUP CHEM REPRO HAZ LIST. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/H*2O FOR AT LEAST 15 MIN. LIFTING UPPER & LOWER LIDS OCCAS. OBTAIN MED ATTN. SKIN: WASH CONTAMD AREA THOROUGHLY W/SOAP & H*2O. APPLY MOISTURIZING HAND CREAM. INHAL: IF AFFECTED. REMOVE I NDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT. ADMINISTER OXYGEN ONLY IF TRAINED. IF BRTHG HAS STOPPED GIVE ARTF RESP. PREFERABLY MOUTH-TO-MOUTH. KEEP PERSON WARM. QUIET & OBTAIN MED ATTN. INGEST: ONLY INDUCE VOMIT AT INSTRUCTION OF MD. KEEP ONLY WARM. QUIET & OBTAIN MED ATTN. OTHER: WHEN USING THIS PROD, DO NOT EAT, DRINK/SMOKE. NOTE: FOLLOWING ANY FIRST AID. MED ADVICE SHOULD BE OBTAIN. (SUP DAT) ===================== Fire Fighting Measures ===================== Flash Point:=-28.9C, -20.F Lower Limits:1.9% Upper Limits:8.5% Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP AND POSSIBLE EXPLOSION WHEN EXPOSED TO EXTREME HEAT. Unusual Fire/Explosion Hazard:SPRAY MIST/VAP FROM CAN PER 400 CUBIC FEET OF AIR MAY REACH LOWER EXPLOSIVE LIMIT & COULD BE IGNITED BY A FLAME/SPARK. NFPA RATING: TYPE OF PAINT: LEAD, HEALTH: 3, FLAMMABILITY: 4, REACTIVITY: 0. PER SONAL PROTECTION: 8. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AREA. WIPE UP WITH INERT MATERIAL. DO NOT FLUSH INTO DRAINS. REMOVE RESIDUE WITH A SUITABLE SOLVENT CLEANER IMMEDIATELY. ====================== Handling and Storage ====================== Handling and Storage Precautions:CONTENTS UNDER PRESSURE. EXPOSURE TO HIGH TEMPERATURES MAY CAUSE BURSTING. AVOID STORING NEAR RADIATOR. STOVE, OPEN FLAME OR DIRECT SUNLIGHT. DO NOT INCINERATE OR PUNCTURE CAN. DO NOT SPRAY INTO FLAME OR ANY INCANDESCENT MATERIAL. Other Precautions:DO NOT SMOKE WHILE USING THIS PRODUCT OR WHERE SOLVENT VAPORS ARE PRESENT. DOL STORAGE CATEGORY: DO NOT STORE AT TEMPERATURE ABOVE 120F. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY NEEDED IF LOCAL EXHAUST IS SATISFACTORY. IF VENTILATION IS INADEQUATE. USE RESPIRATORY MASK APPROVED BY NIOSH FOR PROTECTION AGAINST SPRAY MIST. Ventilation:REQUIREMENTS VARY WITH RATE OR PRODUCT USE. SUPPLEMENT VENTILATION TO KEEP BELOW OSHA AND ACGIH PERMISSIBLE LEVELS OF EACH INGREDIENT. Protective Gloves:SOLVENT RESISTANT GLOVES. Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Supplemental Safety and Health FIRST AID PROC: EXPECIALLY IF SYMPTOMS PERSIST. THRESHOLD VALUE LIMIT: SEE SECTION II. EXPLO HAZ: 3. SERIOUS HAZARD, 4 SEVERE HAZARD, 8 SAFETY GLASSES AND GLOVES. WEIGHT PER GALLON: 10-10.6 LBS. ================== Physical/Chemical Properties ================== Vapor Density:HVR/AIR Spec Gravity:1.20-1.27 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:AEROSOL DISPENSING A PAINT. COLOR DEPENDANT UPON GRADE. CHARACTERISTIC ODOR. Percent Volatiles by Volume:70% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. ALKALI AND ALKALINE EARTH METALS SUCH AS SODIUM. POTASSIUM AND BARIUM. FINE POWDERS OF LIGHT METALS AND THEIR ALLOYS SUCH AS MAGNESIUM. Stability Condition to Avoid:HEAT, SPARKS AND FIRE. Hazardous Decomposition Products:OR BYPRODUCTS: THERMAL DECOMPOSITION MAY YIELD CO, CO*2. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL LAWS. DO NOT PIERCE OR BURN CAN EVEN AFTER USE. =================== MSDS Transport Information =================== Transport Information:DOL STORAGE CATEGORY: DO NOT STORE AT TEMPERATURE ABOVE 120F. ===================== Regulatory Information ===================== SARA Title III Information:SEC 313 SUPPLIER NOTIFICATION: THIS PROD CONTAINS FOLLOWING TOX CHEM SUBJECT TO RPTG REQ OF SEC 313 OF EMER PLANNING & COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372): CAS #: 1309-64-4 CHEM NAME: ANT IMONY (3+) OXIDE % BY WEIGHT UPPER BOUND CONC: 1.25. CAS #: 1344-37-2 CHEM NAME: LEAD SULFOCHROMATE % BY WEIGHT UPPER BOUND CONC: 20. 12656-85-8 CHEM NAME: LEAD MOLYBDATE CHROMATE SULFATE: % BY WEIGHT UPPER BOUND CONC: 0.5. CAS #: 108-88-3 TOLUENE % BY WEIGHT UPPER BOUND CONC: 20. CAS #: 1330-20-7 CHEM NAME: XYLENE % BY WEIGHT UPPER BOUND CONC: 10. CAS #: 100-41-4 CHEM NAME: ETHYLBENZENE % BY WEIG HT UPPER BOUND CONC 2. State Regulatory Information:WARNING: TOLUENE THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE SATATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. WARNING: LEAD, MOLYBDATE, CHROMATE, SULFATE; LEAD SULFOCHROMATE, ANTIMONY (3+) OXIDE. THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. 2-BUTOXYETHANOL CAN BE ABSORBED THROUGH SKIN. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.