GROW GROUP INC -- SUDSY AMMONIA -- 7930-00N051725
===================== Product Identification ===================== Product ID:SUDSY AMMONIA MSDS Date:03/20/1989 FSC:7930 NIIN:00N051725 === Responsible Party === Company Name:GROW GROUP INC Address:760 SOUTH VAIL AVE City:MONTEBELLOW State:CA ZIP:90640 Country:US Info Phone Num:213-724-6530 Emergency Phone Num:800-424-9300(CHEMTREC) Preparer's Name:DONALD GREEN CAGE:0E7P7 === Contractor Identification === Company Name:GROW GROUP INC Address:760 S VAIL AVE City:MONTEBELLO State:CA ZIP:90640 Country:US CAGE:0E7P7 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM HYDROXIDE (SARA III) LD50: (ORAL, RAT) 350 MG/KG CAS:1336-21-6 RTECS #:BQ9625000 Fraction by Wt: < 3% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SUPP DATA: SULFATE OR FLUORINE. EXPLO MATLS CAN RESULT FROM REACTION W/IODINE OR WITH SEVERAL SILVER COMPOUNDS. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: BRTHG IF REQUIRED &/OR HAVE TRAINED PERSON ADMIN OXYGEN IF BRTHG IS DIFFICULT. KEEP WARM & AT (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: REST. CNTCT MD PROMPTLY. INGEST: IF CONSCIOUS, PROMPTLY GIVE LOTS OF DILUTE VINEGAR OR CITRUS JUICE TO (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: DRINK, FOLLOWED BY MILK. DO NOT INDUCE VOMITING. CONTACT PHYSICIAN. RTECS #:9999999ZZ Ingred Name:SPILL PROC: AREA FOR NEUTRALIZATION (DO NOT FLUSH DIRECTLY TO SEWER OR SURFACE WATER). RTECS #:9999999ZZ Ingred Name:WASTE DISP: AMMONIUM HYDROXIDE MIGHT BE CONSIDERED FOR USE IN NEUTRALIZING ACIDIC WASTES. IF DESIRED, AQUEOUS (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: NH*3 CAN BE RECOVERED FROM SCRAP FOR USE OR SALE. RTECS #:9999999ZZ Ingred Name:OTHER PRECS: & FLUSH W/WATER BEFORE DISCARDING. RTECS #:9999999ZZ Ingred Name:EYE PROT: AND WHERE NEEDED, A FACEHIELD OR MASK TO PROTECT AGAINST SPLASHES AND FROM MISTS AND NH*3. RTECS #:9999999ZZ Ingred Name:HYGIENE PRACT: OF VAPS. TRAIN WORKERS IN PROPER HANDLING OF AMMONIUM HYDROXIDE. PREPLACEMENT & PERIODIC MED (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: EXAM IS RECOMM FOR AMMONIA WORKERS & ADDNL EXAMS SHOULD BE PROVIDED IF EXESS EXPOSURE OCCUR. KEEP (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: RECORDS. PRECLUDE FROM EXPOSURE WORKERS WITH EYE OR PULMONARY DISEASE. RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP: AMMONIUM HYDROXIDE SOLUTIONS. EMERGENCY EYE BATH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:SUMMARY OF RISKS: AMMONIUM HYDROXIDE IS IRRIT & CORROSIVE TO BODY TISSUE. EXCESSIVE INHAL OF VAPORS IS IRRIT TO THE MUCOUS MEMB OF THE RESP TRACT & CAN RESULT IN HDCH, COUGH, SEV LUNG CONGESTION (EDEM A AND DIFFICULTY IN BRTHG). SKIN CONTACT W/LIQ CAN IRRIT, REDDEN & CAUSE BURNS. LIQ CNTCT W/THE EYES (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: CAN BE SEVERELY DAMAGING AND CAN RESULT IN LOSS OF VISION. INGESTION IS CORROSIVE TO THE DIGESTIVE TRACT. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE: IMMED FLUSH W/LOTS OF RUNNING WATER FOR AT LEAST 15 MIN, INCL UNDER EYELIDS, THEN CONTACT PHYSICIAN IMMED, PREFERABLY AN OPTHALMOLOGIST. SPEED & THORO IN RINSING EYES IS IMPORTANT TO AVOID PERMAN ENT INJURY. SKIN: IMMED FLUSH W/LOTS OFWATER WHILE REMOVING CONTAM CLTHG & SHOES. GET MED HELP PROMPTLY IF LARGE AREAS ARE AFFECTED OR IRRIT PERSISTS. INHAL: REMOVE TO FRESH AIR. RESTORE (ING 3) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE MEDIA APPROP TO SURROUNDING FIRE CNDTNS. USE COLD WATER SPRAY TO CONTROL VAPS & COOL FIRE-EXPOSED CNTNRS.(SUPP DATA) Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:WHEN HEATED, MATL WILL EMIT NH*3 VAPORS WHICH NECESSITATES RESP & EYE PROTECTION FOR FIREFIGHTERS. ================== Accidental Release Measures ================== Spill Release Procedures:PREPARE WRITTEN PLANS FOR EMER. INFORM SAFETY PERSONNEL OF LRG SPILLS & EVAC AREA. PROVIDE VENT. THOSE INVOLVED IN CLEAN-UP NEED PROT AGAINST CNTCT W/LIQ & INHAL OF MIST OR VAPS. CNTN SPILL FOR RECOVE RY WHEN FEASIBLE OR FLUSH W/WATER TO (ING 6) Neutralizing Agent:SEE WASTE DISPOSAL. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL (<80F TO AVOID PRESSURIZATION >1 ATM) AREA IN CLOSED CNTNRS, AWAY FROM SOURCES OF HEAT, DIRECT SUNLIGHT, & INCOMPATIBLE MATLS. Other Precautions:HANDLE AS A CORROSIVE LIQUID. PREVENT DAMAGE TO CNTNRS. >50F, THE AMMONIA VAPOR FROM THIS MATL CAN BE A SERIOUS HAZ IN A SPILL SITUATION. USE CAUTION WHEN OPENING SEALED CNTNRS FOR PROPER PRESSURE REL IEF. DRAIN EMPTIED CNTNRS WELL (ING 9) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR EMER & NONROUTINE CNDTNS ABOVE TLV, A NIOSH/MSHA APPROVED CHEM CARTRIDGE RESP W/A FULL FACEPIECE RESP IS SUITABLE FOR EXPOSURE BELOW 300 PPM; >300 PPM OR IF CONC IS UNKNOWN, USE NIOSH/MSHA APPROVE D SELF-CONTAINED RESP W/FULL FACEPIECE. Ventilation:PROVIDE GENERAL & LOCAL EXHAUST VENTILATION AS REQUIRED TO MEET TLV. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:SPLASH-PROOF, CHEM SAFETY GOGGS,(ING 10) Other Protective Equipment:RUBBER SUIT, BOOTS, GLOVES, APRON, OR OTHER PROT CLTHG AS REQUIRED FOR WORKPLACE CNDTNS TO PVNT CNTCT WITH (ING 14) Work Hygienic Practices:WORK PRACTS & EQUIP MUST BE ARRANGED TO PVNT CNTCT OF AMMONIUM HYDROXIDE W/THE WORKER'S BODY & TO AVOID INHAL(ING 11) Supplemental Safety and Health SPEC GRAV: 0.982 +/- 0.003 (H*2O=1). APPEAR/ODOR: DETECTABLE AT 5 PPM & IRRIT AT 25-50 PPM OF NH*3, PROVIDES WARNING OF HAZ CONCS IN AIR. PH: 11.8+/-0.3. EXTING MEDIA: MATL ITSELF IS NOT FLAMM. MATLS TO AVOID: ALUMINUM, & THEIR ALLOYS & W/GALVANIZED SURFS. VIOLENT RXNS CAN OCCUR, FOR EXAMPLE, W/DIMETHYL (ING 2) ================== Physical/Chemical Properties ================== Vapor Pres:420-475 Spec Gravity:SUPP DATA pH:SUPDAT Solubility in Water:100% Appearance and Odor:A COLORLESS TO CLOUDY LIQ W/AN ODOR OF AMMONIA. THE ODOR WHICH IS (SUPP DATA) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AMMONIUM HYDROXIDE IS STRONGLY ALKALINE AND IS INCOMPATIBLE WITH ACID MATERIALS AND WITH COPPER, TIN, ZINC, (SUPP DATA) Stability Condition to Avoid:ADDING NAOH TO THIS MATERIAL AND/OR HEATING WILL VOLATIZE NH*3. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:FOLLOW FED, STATE & LOC REGS FOR PH, NH*3 CONTENT, & SALTS CONTENT FOR EFFLUENTS. AMMONIUM HYDROXIDE CAN BE DILUTED W/WATER, NEUTRALIZED AS REQUIRED W/DILUTE HCL OR DILUTE H*2SO*4, AND THEN HIGHLY DIL UTED W/WATER FOR DISCHARGE. SUITABLE SCRAP (ING 7) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.